Organocatalytic cascade reaction of aliphatic enals and benzoylnitromethane: synthesis of enantioenriched tetrasubstituted cyclohexene carbaldehyde

Vista sencilla de ítem
dc.contributor.authorDavid Rodriguez, Fredy A.
dc.contributor.authorMaldonado Villamil, Mauricio
dc.contributor.authorGuevara Pulido, James
dc.contributor.orcidGuevara Pulido, James [0000-0001-9134-3719]
dc.date.accessioned2020-08-04T17:29:06Z
dc.date.available2020-08-04T17:29:06Z
dc.date.issued2020
dc.description.abstractenglishA new example of the reactivity of enals with benzoylnitromethane was studied in a Michael-Michael-Aldol-Dehydration quadruple organocascade reaction. The reaction unexpectedly yielded a tetrasubstituted cyclohexene carbaldehyde with excellent enantiomeric excess when crotonaldehyde was used as the Michael-acceptor, whereas using (E)-Hex-2-enal as the Michael-acceptor formed a cyclic hemiacetal by steering the reaction into the intramolecular formation of the same intermediate via a Michael-Heterocyclization domino reaction.eng
dc.format.mimetypeapplication/pdf
dc.identifier.doihttps://doi.org/10.1155/2020/9248793
dc.identifier.instnameinstname:Universidad El Bosquespa
dc.identifier.issn2090-9071
dc.identifier.reponamereponame:Repositorio Institucional Universidad El Bosquespa
dc.identifier.repourlhttps://repositorio.unbosque.edu.co
dc.identifier.urihttps://hdl.handle.net/20.500.12495/3665
dc.language.isoeng
dc.publisherHindawispa
dc.publisher.journalJournal of chemistryspa
dc.relation.ispartofseriesJournal of chemistry, 2090-9071, Vol. 2020spa
dc.relation.urihindawi.com/journals/jchem/2020/9248793/
dc.rightsAttribution 4.0 International*
dc.rights.accessrightshttps://purl.org/coar/access_right/c_abf2
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.accessrightsAcceso abierto
dc.rights.creativecommons2020-06-28
dc.rights.localAcceso abiertospa
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subject.decsReacciones químicasspa
dc.subject.decsCatálisisspa
dc.subject.decsEnzimasspa
dc.titleOrganocatalytic cascade reaction of aliphatic enals and benzoylnitromethane: synthesis of enantioenriched tetrasubstituted cyclohexene carbaldehydespa
dc.title.translatedOrganocatalytic cascade reaction of aliphatic enals and benzoylnitromethane: synthesis of enantioenriched tetrasubstituted cyclohexene carbaldehydespa
dc.type.coarhttps://purl.org/coar/resource_type/c_6501
dc.type.driverinfo:eu-repo/semantics/article
dc.type.hasversioninfo:eu-repo/semantics/publishedVersion
dc.type.localArtículo de revista

Archivos

Bloque original
Mostrando 1 - 1 de 1
Miniatura
Nombre:
Fredy A. David Rodriguez , Mauricio Maldonado Villamil_2020.pdf
Tamaño:
1.35 MB
Formato:
Adobe Portable Document Format
Descripción:
Descargar
Bloque de licencias
Mostrando 1 - 1 de 1
No hay miniatura disponible
Nombre:
license.txt
Tamaño:
1.71 KB
Formato:
Item-specific license agreed upon to submission
Descripción:
Descargar

Colecciones

Artículos